Relation between Surface Hydrophobic Effect of Activated Carbons and the Immersion Enthalpies in Phenol, 4-Nitro Phenol and 3-Chloro Phenol Aqueous Solutions
No. 30 (2009-11-01)Author(s)
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Liliana GiraldoPhD. Profesora Asociada. Departamento de Química, Facultad de Ciencias. Universidad Nacional de Colombia. Bogotá D.C., Colombia. lgiraldogu@unal.edu.co
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Juan Carlos MorenoPhD. Profesor Titular. Departamento de Química. Facultad de Ciencias. Universidad de los Andes. Bogotá D.C., Colombia. jumoreno@uniandes.edu.co
Abstract
For five activated carbons, obtained from lignocellulosic materials the, immersion enthalpies in phenolic solutions are determined. The activated carbons have basic character with values of pH in the point of zero charge, pHPZC, between 7.4 and 9.7. The immersion enthalpies of activated carbons in CCl4 and water are determined, from these results the hydrophobic factor, hf, are calculated, that change between 2.98 and 6.75. The immersion enthalpies of the activated carbons in phenol, 4-nitro phenol and 3-chloro phenol solutions are between 7.6 y 13.9; 12.7 y 20.5; 6.8 y 11.4 Jg-1 respectively
Keywords:
Acidity and basicity, immersion calorimetry, pHPZC, immersion enthalphy, phenols adsorption